DNP of high spin radicals with a spin 1/2 sensitizer

Santiago Bussandri Mattia – @SantiBussandri

Presenting this new DNP development using high spin radicals systems at #GlobalnmrTC2022!! Thanks to the teamwork with Kan Tagami, @asifequbal313, Andrez Rajca and @songihanlab. @global_nmr. Download full poster: https://t.co/0zUrECokSL pic.twitter.com/j289fTBt3f

— Santiago Bussandri (@SantiBussandri) August 3, 2022

High-spin paramagnetic systems do not give rise to DNP effects by themselves, but in theory, this can be achieved by mixing these radicals with spin 1/2 radicals. In this work, we seek to demonstrate DNP using a mixture of spin 1/2 and higher spin radicals at high magnetic field.